Hypervalent iodine in synthesis XXXIII: Palladium-catalyzed cross- coupling reaction of potassium aryltrifluoroborates with diaryliodonium salts and hydroxy(tosyloxy)iodobenzene

Article abstract of DOI:10.1080/00397919908086252

Potassium aryltrifluoroborates react smoothly with diaryliodonium salts and hydroxy(tosyloxy)iodobenzene, PhI(OH)OTs, under mild conditions in the presence of a palladium catalyst and without added base to afford biaryls in excellent yields.

Full text of DOI:10.1080/00397919908086252

This article was downloaded by: [Stony Brook University]
On: 22 October 2014, At: 15:50
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic Organic
Chemistry
Publication details, including instructions for authors and
subscription information:
http://www.tandfonline.com/loi/lsyc20
Hypervalent Iodine in Synthesis
XXXIII: Palladium-Catalyzed
Cross-Coupling Reaction of
Potassium Aryltrifluoroborates
with Diaryliodonium Salts and
Hydroxy(tosyloxy)iodobenzene
a
a
Min Xia & Zhen-Chu Chen
a
Department of Chemistry , Hangzhou University ,
Hangzhou, 310028, P.R. China
Published online: 17 Sep 2007.
To cite this article: Min Xia & Zhen-Chu Chen (1999) Hypervalent Iodine in Synthesis
XXXIII: Palladium-Catalyzed Cross-Coupling Reaction of Potassium Aryltrifluoroborates with
Diaryliodonium Salts and Hydroxy(tosyloxy)iodobenzene, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 29:14,
2457-2465, DOI: 10.1080/00397919908086252
To link to this article: http://dx.doi.org/10.1080/00397919908086252
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the information
(
&
the “Content”) contained in the publications on our platform. However, Taylor
Francis, our agents, and our licensors make no representations or warranties
whatsoever as to the accuracy, completeness, or suitability for any purpose of the
Content. Any opinions and views expressed in this publication are the opinions and

views of the authors, and are not the views of or endorsed by Taylor & Francis. The
accuracy of the Content should not be relied upon and should be independently
verified with primary sources of information. Taylor and Francis shall not be liable
for any losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or indirectly in
connection with, in relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study purposes. Any
substantial or systematic reproduction, redistribution, reselling, loan, sub-licensing,
systematic supply, or distribution in any form to anyone is expressly forbidden.
Terms & Conditions of access and use can be found at http://www.tandfonline.com/
page/terms-and-conditions