Gas chromatographic investigation of the boron trifluoride etherate-induced formation and anomerization of glucopyranosides

Article abstract of DOI:10.1080/07328309808002351

Boron trifluoride etherate-induced glucosylation of methanol, 1-propanol, 2-propanol, 2-bromoethanol, and 3-bromo-2-(bromomethyl)propan-1-o1, using 1,2,3,4,6-penta-O-acetyl-β-D-glucopyranose as donor, gave the corresponding β-glucopyranosides. The α-glucosides and 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose were formed as byproducts in varying amounts, according to GLC analysis. The propensity of the different glucopyranosides to anomerize was determined in separate experiments.

Full text of DOI:10.1080/07328309808002351

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Journal of Carbohydrate Chemistry
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Gas Chromatographic Investigation
of the Boron Trifluoride Etherate-
Induced Formation and Anomerization of
Glucopyranosides
a
a
a
Ulf Ellervik , Karl Jansson & Göran Magnusson
a
Organic Chemistry 2 , Center for Chemistry and Chemical
Engineering, University of Lund , P. O. Box 124, S-221 00, Lund,
Sweden
Published online: 22 Aug 2006.
To cite this article: Ulf Ellervik , Karl Jansson & Göran Magnusson (1998) Gas Chromatographic
Investigation of the Boron Trifluoride Etherate-Induced Formation and Anomerization of
Glucopyranosides , Journal of Carbohydrate Chemistry, 17:4-5, 777-784
To link to this article: http://dx.doi.org/10.1080/07328309808002351
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