Journal of Fluorine Chemistry p. 195 - 198 (1994)
Update date:2022-08-10
Topics:
Gerus, I. I.
Gorbunova, M. G.
Kukhar, V. P.
We have found readily available β-ethoxyvinyl trifluoromethyl ketone to be a convenient and comprehensive starting material for the synthesis of various fluoro-containing compounds such as heterocycles, enones, enaminones and chelate complexes.The 4,4,4-trifluoro-3-oxo-1-butenyl group formed by β-ethoxyvinyl trifluoromethyl ketone is a suitable protecting group for the N-H terminal of amino acids in peptide synthesis.The formation of peptides using these protected amino acids occurs without racemization. - Keywords: β-Ethoxyvinyl polyfluoroalkyl ketones; Synthones; Protecting group; Peptide synthesis; Reactions
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