Journal of Organic Chemistry p. 2897 - 2900 (1983)
Update date:2022-08-12
Topics:
Go, Celia Lee
Waddell, Walter H.
The reaction of phenylnitrene with oxygen was reinvestigated by irradiating phenyl azide (1) in O2-saturated acetonitrile solutions.Quantum yields of the disappearance of 1 are calculated from absorption spectral changes, and primary photoproducts are determined by using high-pressure liquid chromatography.The photochemistry of the reaction products (azobenzene, azoxybenzene, nitrobenzene, and nitrosobenzene) are also examined, including measurements of quantum yields and determinations of primary photoproducts and product ratios.A reaction sequence is presented to account for the photooxidation products afforded upon irradiation of 1 in the presence of oxygen.The reaction of phenylnitrene with oxygen is an effective termination step in the autocatalytic chain decomposition of 1.
View More
website:http://www.shtopchem.com/
Contact:0086-0576-87776998
Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Shantou Baokang Pharmaceutical Co., Ltd.
Contact:+86-754-88873487
Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
SHANGHAI RC CHEMICALS CO.,LTD.
website:http://www.rcc.net.cn
Contact:+86-21-50322175
Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Airsea(Taizhou) Pharmaceutical Limited(expird)
Contact:+86-576-88057622
Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016
Doi:10.1515/HC.2008.14.4.269
(2008)Doi:10.1016/0040-4039(95)00809-Q
(1995)Doi:10.1016/j.apcata.2017.05.025
(2017)Doi:10.1016/j.bmc.2008.02.083
(2008)Doi:10.1080/10426507.2017.1395438
(2018)Doi:10.1007/s00706-009-0235-2
(2010)
