Bulletin of the Chemical Society of Japan p. 4151 - 4152 (1988)
Update date:2022-08-11
Topics:
Itoh, Kenji
Miura, Masahiro
Nomura, Masakatsu
Tetracarbonylcobaltate ion generated by a treatment of cobalt(II) chloride with either sodium sulfide or sodium borohydride under a normal pressure of carbon monoxide was capable of catalyzing carbonylation of aryl halides in the presence of calcium hydroxide and methyl iodide to give arylglyoxylic acids in good selectivity.
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