Phosphorus, Sulfur and Silicon and the Related Elements p. 245 - 258 (1997)
Update date:2022-08-05
Topics:
Vallee, Yannick
Chavant, Pierre-Yves
Pinet, Sandra
Pelloux-Leon, Nadia
Arnaud, Roger
Barone, Vincenzo
Thiocarbonyl compounds, such as thioaldehydes and thioketones, are good dienophiles in the Diels-Alder reaction. Here we show that suitably substituted thioformamides can also be used in this reaction. A theoretical study of the [4π + 2π] cycloaddition of thiocarbonyls with butadiene has been performed and was used to determine the needed substituents.
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