Inorganic Chemistry p. 126 - 129 (1964)
Update date:2022-08-16
Topics:
Penneman
Sturgeon
Asprey
Solid fluoride complexes of pentavalent uranium are formed by heating UF5 with ammonium or alkali fluorides under anhydrous conditions. A series of complexes having MF:UF5 ratios (M = NH4, Li, Na, K, Rb, and Cs) of 1:1, 2:1 (except Li and Na), and 3:1 (except Li) were characterized by X-ray powder diffraction. These white to pale blue compounds exhibit characteristic absorption in the 1.3 to 1.5 μ region.
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(1968)
