Preparation and Properties of Ethylpalladium Thiolate Complexes. Reaction with Organic Halides leading to C-S Bond Formation; Crystal Structure of trans-

DOI: 10.1039/DT9910000759

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Journal of the Chemical Society, Dalton Transactions p. 759 - 764 (1991)

Update date:2022-08-22

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Authors:

Osakada, Kohtaro

Ozawa, Youichi

Yamamoto, Akio

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Article abstract of DOI:10.1039/DT9910000759

The complexes trans- (R=Ph, 1; or C6H4Me-p, 2) and trans- 3 have been prepared by reactions of trans- or trans- with allyl aryl sulphides.Complex 1 reacts with various organic halides such as allyl chloride, benzyl bromide and methyl iodide to give allyl phenyl sulphide and methyl phenyl sulphide, respectively; trans- (X=Cl, 4; B3, 5; or I, 6) were isolated from the reaction mixtures.The complexe trans- also reacts with allyl chloride to give allyl phenyl ether together with complex 4.The structure of complex 5 has been determined by X-ray crystallography: orthorhombic, space group Pbca with a=12.306(3), b=20.078(5), c=11.753(2) Angstroem, Z=8, R=0.036 and R'=0.042.It has a square-planar co-ordination around the palladium centre.The reaction of allyl chloride with complex 1 in toluene obeys first-order kinetics in the concentrations of both allyl chloride and 1.

Full text of DOI:10.1039/DT9910000759

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