Di(lithiomethyl)benzenes from di(chloromethyl)benzenes by a DTBB-catalysed lithiation under Barbier-type conditions

DOI: 10.1016/S0040-4020(97)00878-8

Source and publish data:

Tetrahedron p. 13897 - 13904 (1997)

Update date:2022-08-17

Topics:

Authors:

Gomez, Cecilia

Huerta, Fernando F.

Yus, Miguel

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Article abstract of DOI:10.1016/S0040-4020(97)00878-8

The reaction of 1,2-, 1,3- and 1,4-di(chloromethyl)benzenes (1a-c) and different electrophiles [Pr(i)CHO, Bu(t)CHO, PhCHO, (CH₂)₅CO, PhCOMe, Me₃SiCl] with an excess of lithium powder and a catalytic amount of DTBB (4 mol%)

Full text of DOI:10.1016/S0040-4020(97)00878-8

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