Journal of the American Chemical Society p. 2548 - 2554 (1988)
Update date:2022-08-10
Topics:
Dauben, William G.
Share, Paul E.
Ollmann, Richard R., Jr.
The origin of the wavelenght dependent photochemical behavior of previtamin D3 was investigated.The fluorescence spectrum and quantum yield of previtamin D3 were determined at 302 and 307 nm, and both the intensity distribution and the fluorescence quantum yields were found to be independent of excitation energy.A large Stokes shift was observed which is consistent with an excited state torsional relaxation about the central double bond of the triene.The excited state displacement was reproduced by QCFF/PI calculations of the ground and excited states of a model compound.The excited state involved in the absorption and emission spectra is discussed.
View More
Shaanxi Lighte Optoelectronics Material Co., Ltd.
Contact:+86-29-88320728-622/619/620
Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Jinan Jinguilin Chemical Co.,Ltd
Contact:+86-531-81188412
Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Liao Cheng All Win Chemicals Co.,LTD
Contact:86+0635-2991582
Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Zhejiang Linhai Xinhua Chemicals Factory
Contact:0086-13661858911
Address:Xunqiao Development Zone, Linhai, Zhejiang, China
WEIFANG RICHEM INTERNATIONAL LTD
Contact:86-536-2222176
Address:weifang,shandong
Doi:10.1080/00397910902906529
(2009)Doi:10.1246/bcsj.55.842
(1982)Doi:10.1039/J19690000756
()Doi:10.1021/acs.inorgchem.9b02676
(2019)Doi:10.1002/jhet.64
(2009)Doi:10.1021/ja01268a025
(1938)
