Tetrahedron p. 12319 - 12338 (1997)
Update date:2022-08-03
Topics:
Booker-Milburn, Kevin I.
Cowell, Justin K.
Harris, Laurence J.
A concise synthesis of 7-desmethylasteriscanolide is described. The key features include an efficient intramolecular [2+2] photocycloaddition of the α,β-unsaturated acid-ether 29 followed by a Curtius rearrangement/ruthenium tetroxide/fragmentation sequen
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