High Yields of Nitrene Insertion into Unactivated C-H Bonds. First Example of X-Ray Crystallographic and 19F NMR Analysis of the Photochemically Produced C-H Inserted Adduct

DOI: 10.1039/c39940001841

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1841 - 1842 (1994)

Update date:2022-08-17

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Authors:

Pandurangi, Raghoottama S.

Katti, Kattesh V.

Barnes, Charles L.

Volkert, Wynn A.

Kuntz, Robert R.

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Article abstract of DOI:10.1039/c39940001841

Photolysis of 4-azido-tetrafluorobenzonitrile results in the highest yield reported to date, (75 - 80percent as estimated from 19F NMR spectroscopy) for nitrene insertion into the unactivated C-H bond of cyclohexane; the photochemical adduct is characteri

Full text of DOI:10.1039/c39940001841

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