Journal of the Chemical Society. Perkin transactions I p. 2145 - 2149 (1996)
Update date:2022-08-11
Topics:
Yokoyama, Masataka
Nomura, Mitsuru
Togo, Hideo
Seki, Hiroko
The coupling reaction of a D-ribofuranosyl fluoride with indoles in the presence of boron trifluoride gives the corresponding C-nucleosides in a stereoselective manner depending upon reaction temperatures and solvents: the β-anomer is preferred under such conditions as -15 to -40°C in nitroethane while the α-anomer is preferred at -78°C in propiononitrile.
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