Journal of Organic Chemistry p. 5748 - 5751 (1994)
Update date:2022-08-11
Topics:
Toda, Fumio
Tanaka, Koichi
Stein, Zafra
Goldberg, Israel
Racemic 2,2'-dihydroxy-1,1'-binaphyl and 10,10'-dihydroxy-9,9'-biphenanthryl have been resolved effectively by crystalline complexation with commercially available N-alkylcinchonidium halides.The resolved complexes were studied by X-ray diffraction methods in order to characterize the intermolecular interaction and recognition schemes.The results indicate the significance of directional hydrogen bonding and aryl-aryl interaction modes in the molecular recognition process.
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