Enantiocontrol by intrinsic antiparallel double repulsion on diacetone-Dglucose template. Enantioselective synthesis of alanine and chirally deuterated glycine

DOI: 10.1016/S0040-4039(00)93559-7

Source and publish data:

Tetrahedron Letters p. 5801 - 5804 (1991)

Update date:2022-08-11

Topics:

Authors:

Kakinuma, Katsumi

Koudate, Takashi

Li, Hui-Ying

Eguchi, Tadashi

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Article abstract of DOI:10.1016/S0040-4039(00)93559-7

A divergent and highly enantioselective synthetic methodology not only for both enantiomers of α-amino acids but for both chirally deuterated glycines from a single starting material was developed by making use of stereocontrol with antiparallel double repulsion on the diacetone-D-glucos-3-ulose template.

Full text of DOI:10.1016/S0040-4039(00)93559-7

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