N-Hydroxyphthalimide (NHPI)-catalyzed reaction of adamantane under nitric oxide atmosphere

DOI: 10.1016/S0040-4039(97)01652-3

Source and publish data:

Tetrahedron Letters p. 7075 - 7078 (1997)

Update date:2022-08-25

Topics:

Authors:

Sakaguchi, Satoshi

Eikawa, Masahiro

Ishii, Yasutaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01652-3

The reaction of adamantane under atmospheric nitric oxide in the presence of N-hydroxyphthalimide (NHPI) which serves as the radical catalyst in a mixed solvent of benzonitrile and acetic acid afforded 1-N-adamantylbenzamide as a principal product along with small amounts of 1-nitroadamantane and 1-hydroxyadamantane. On the other hand, 1-nitroadamantane was obtained in good yield upon treatment of adamantane with NO/O₂.

Full text of DOI:10.1016/S0040-4039(97)01652-3

Products guided by the article

Product name:N-(1-Adamantyl)benzamide

Cas No:19026-84-7

R&D Labs maybe for 19026-84-7

Chengdu NoVi Biotechnology Co., Ltd.(expird)

Contact:13551243286/028-81458053

Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203

Relevant to this article

Cobalt(II) Nitrosyl Cation Radicals of Porphyrins, Chlorins, and Isobacteriochorins. Models for Nitrite and Sulfite Reductases and Implications for A_1u Heme Radicals

Doi:10.1021/ja00311a073
(1985)
Practical Aerobic Oxidation of Alcohols: A Ligand-Enhanced 2,2,6,6-Tetramethylpiperidine-1-oxy/Manganese Nitrate Catalyst System

Doi:10.1002/cctc.201700710
(2017)
Gas-Phase Dehydration of Glycerol into Acrolein in the Presence of Polyoxometalates

Doi:10.1134/S0023158420030064
(2020)
Quantification of electrochemically generated iodine-containing metabolites using inductively coupled plasma mass spectrometry

Doi:10.1021/ac801878k
(2008)
An Improved Rapid and Mild Deoxygenation of Amine N-oxides

Doi:10.1002/jhet.3069
(2018)
The mechanism of the tertiary amine catalysed isomerisation of endoperoxides to hydroxyketones: Synthesis and chemistry of the intermediate postulated in the peroxide attack mechanism

Doi:10.1016/S0040-4039(02)02374-2
(2002)

Article Doi