Journal of the Chemical Society - Faraday Transactions p. 3601 - 3608 (1994)
Update date:2022-08-10
Topics:
Herrebout, W. A.
Veken, B. J. van der
The equilibrium geometry, relative stability and vibrational frequencies for the 1:2 van der Waals complexes between CH3Cl and HCl have been investigated using MP2/6-31 + G** ab initio calculations.The results are used to interpret the IR spectrum of the 1:2 complex observed in solutions of CD3Cl-HCl mixtures dissolved in liquefied argon, and show that in these solutions the chain complex CD3Cl*HCl*HCl is formed.
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