Synthesis of Homoallylamines by the Addition of Allylic Indium Reagents to Azomethines and Nitriles

Article abstract of DOI:10.1246/bcsj.66.1528

Triallyldiindium trihalides and allylindate(1-)s reacted with N-benzylideneamines regioselectively at the C-3 carbon on the allyl group to give high yields of homoallylic secondary amines.Primary amines were obtained by the action of an excess of allylic