Highly Stereoselective Synthesis of Vinylsilanes from Carbonyl Compounds

DOI: 10.1055/s-1988-27526

Source and publish data:

Synthesis p. 234 - 236 (1988)

Update date:2022-08-17

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Authors:

Barluenga, Jose

Fernandez-Simon, Jose L.

Concellon, Jose M.

Yus, Miguel

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Article abstract of DOI:10.1055/s-1988-27526

The in situ generated (chlorolithiomethyl)trimethylsilane reacts at -60 deg C to -45 deg C with different aldehydes or ketones 1 to afford, after lithation with lithium naphthalenide at -78 deg C to 20 deg C, vinylsilanes 5a-h in a stereoselective manner.

Full text of DOI:10.1055/s-1988-27526

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Product name:trimethyl[(Z)-2-phenylethenyl]silane

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