Reactions of trihalo(phenylenedioxy)phosphoranes with arylacetylenes: IX.* reaction of 2,2,2-trichloro-1,3,2λ5- benzodioxaphosphole with 1-iodo-2-phenylethyne

Article abstract of DOI:10.1134/S1070428006010180

According to NMR data, the reaction of 2,2,2-trichloro-1,3, 2λ⁵-benzodioxaphosphole with 1-iodo-2-phenylethyne leads to formation of 2,6- and 2,8-dichloro-3-iodo-4-phenyl-1,2λ⁵- benzoxaphosphinine 2-oxides which undergo partial hydro

Full text of DOI:10.1134/S1070428006010180

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GXOOLQꢄꢂ $ꢊ7ꢊꢄꢂ 3HWURYꢄꢂ 5ꢊ5ꢊꢄꢂ 6KW\UOLQDꢄꢂ $ꢊ$ꢊꢄꢂ =\DEOLNRꢇꢂ
YDꢄꢂ 7ꢊ$ꢊꢄꢂ 0XVLQꢄꢂ 5ꢊ=ꢊꢄꢂ $]DQFKHHYꢄꢂ 1ꢊ0ꢊꢄꢂ DQGꢂ ,O¶\Dꢇꢂ
VRYꢄꢂ$ꢊ9ꢊꢄꢂSˆ††ꢃꢁEꢃꢁBrꢃꢁ8ur€ꢊꢄꢂꢀꢒꢒꢁꢄꢂYROꢊꢂꢉꢁꢄꢂSꢊꢂꢀꢆꢀꢆꢊꢂ
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QRYꢄꢂ,ꢊ$ꢊꢄꢂ*XEDLGXOOLQꢄꢂ$ꢊ7ꢊꢄꢂ9DUDNVLQDꢄꢂ(ꢊ1ꢊꢄꢂDQGꢂ.RQRYDꢇ
ORYꢄꢂ$ꢊ,ꢊꢄꢂD“‰ꢃꢁS‚††ꢃꢁ6xhqꢃꢁIhˆxꢂꢁTrꢀꢃꢁFuv€ꢊꢄꢂꢃꢅꢅꢀꢄꢂSꢊꢂꢉꢉꢉꢊꢂ
ꢉꢊꢂ0LURQRYꢄꢂ9ꢊ)ꢊꢄꢂ *XEDLGXOOLQꢄꢂ$ꢊ7ꢊꢄꢂ 6KW\UOLQDꢄꢂ$ꢊ$ꢊꢄꢂ /LWYLꢇ
ꢈꢊꢂ0LURQRYꢄꢂ 9ꢊ)ꢊꢄꢂ /LWYLQRYꢄꢂ ,ꢊ$ꢊꢄꢂ 6KW\UOLQDꢄꢂ $ꢊ$ꢊꢄꢂ *XEDLꢇ
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QRYꢄꢂ,ꢊ$ꢊꢄꢂ3HWURYꢄꢂ5ꢊ5ꢊꢄꢂ.RQRYDORYꢄꢂ$ꢊ,ꢊꢄꢂ'REU\QLQꢄꢂ$ꢊ%ꢊꢄꢂ
=\DEOLNRYDꢄꢂ7ꢊ$ꢊꢄꢂ0XVLQꢄꢂ5ꢊ=ꢊꢄꢂDQGꢂ0RUR]RYꢄꢂ9ꢊ,ꢊꢄꢂSˆ††ꢃꢁ
EꢃꢁBrꢃꢁ8ur€ꢊꢄꢂꢃꢅꢅꢃꢄꢂYROꢊꢂꢎꢃꢄꢂSꢊꢂꢀꢎꢉꢆꢊꢂ
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ꢂ
ꢂ
GXOOLQꢄꢂ $ꢊ7ꢊꢄꢂ 3HWURYꢄꢂ 5ꢊ5ꢊꢄꢂ .RQRYDORYꢄꢂ $ꢊ,ꢊꢄꢂ $]DQFKHꢇꢂ
HYꢄꢂ 1ꢊ0ꢊꢄꢂ DQGꢂ 0XVLQꢄꢂ 5ꢊ=ꢊꢄꢂ Sˆ††ꢃꢁ Eꢃꢁ Brꢃꢁ 8ur€ꢊꢄꢂ ꢃꢅꢅꢅꢄꢂ
YROꢊꢂꢎꢅꢄꢂSꢊꢂꢀꢅꢆꢉꢊꢂ
ꢎꢊꢂ0LURQRYꢄꢂ 9ꢊ)ꢊꢄꢂ 6KW\UOLQDꢄꢂ $ꢊ$ꢊꢄꢂ *XEDLGXOOLQꢄꢂ $ꢊ7ꢊꢄꢂ %RJꢇ
ꢆꢊꢂ0LURQRYꢄꢂ 9ꢊ)ꢊꢄꢂ 3HWURYꢄꢂ 5ꢊ5ꢊꢄꢂ 6KW\UOLQDꢄꢂ $ꢊ$ꢊꢄꢂ *XEDLGXOꢇ
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GDQRYꢄꢂ $ꢊ9ꢊꢄꢂ /LWYLQRYꢄꢂ ,ꢊ$ꢊꢄꢂ $]DQFKHHYꢄꢂ 1ꢊ0ꢊꢄꢂ /DW\ꢇꢂ
SRYꢄꢂ6Kꢊ.ꢊꢄꢂ0XVLQꢄꢂ5ꢊ=ꢊꢄꢂDQGꢂ(IUHPRYꢄꢂ<Xꢊ<DꢊꢄꢂD“‰ꢃꢁS‚††ꢃꢁ
6xhqꢃꢁIhˆxꢂꢁTrꢀꢃꢁFuv€ꢊꢄꢂꢃꢅꢅꢆꢄꢂSꢊꢂꢀꢁꢉꢊꢂ
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ꢂ
OLQꢄꢂ $ꢊ7ꢊꢄꢂ /LWYLQRYꢄꢂ ,ꢊ$ꢊꢄꢂ 0XVLQꢄꢂ 5ꢊ=ꢊꢄꢂ DQGꢂ .RQRYDꢇꢂ
ORYꢄꢂ$ꢊ,ꢊꢄꢂSˆ††ꢃꢁEꢃꢁBrꢃꢁ8ur€ꢊꢄꢂꢃꢅꢅꢀꢄꢂYROꢊꢂꢎꢀꢄꢂSꢊꢂꢉꢎꢊꢂ
5866,$1ꢂꢂ-2851$/ꢂꢂ2)ꢂꢂ25*$1,&ꢂꢂ&+(0,675<ꢂꢂꢂ9ROꢊꢂꢂꢆꢃꢂꢂꢂ1Rꢊꢂꢂꢀꢂꢂꢂꢃꢅꢅꢉꢂ