Magnetic Resonance in Chemistry p. 368 - 376 (1989)
Update date:2022-08-17
Topics:
Orrell, Keith G.
Stephenson, David
Rault, Thierry
The monomer-dimer equilibria of 2,6- and 3,5-dimethylnitrosobenzenes in CDCl3 solution were investigated by 1H and/or 13C NMR spectroscopy.The mixed systems nitrosobenzene + 2,6-dimethylnitrosobenzene and 2,6-dimethylnitrosobenzene + 3,5-dimethylnitrosobenzene were also studied, and mixed azodioxy dimers were identified.In all systems exchange occurs exclusively between dimer and monomer species, rates and activation energies being calculated from time-dependent 1H 1D spectra and/or 1H 2D-EXSY spectra measured at different temperatures. KEY WORDS 1H NMR 13C NMR 2,6-Dimethylnitrosobenzene 3,5-Dimethylnitrosobenzene Monomer-dimer equilibria Mixed azodioxy dimers
View More
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
Xiamen XM-Innovation Chemical Co., Ltd
Contact:+86-592-3216205
Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd
Contact:+86-536-8566856
Address:Shouguang,Shandong,China
Shanghai Zhihua ChemTech Co., Ltd.
Contact:+86-13774313779
Address:Room 817 Suite B 3333 Shenjiang Road
Disynthesis Chemical Technology Co. Ltd.
Contact:+86-571-88194596
Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Doi:10.1016/j.bmc.2015.07.039
(2015)Doi:10.1021/ja00318a014
(1984)Doi:10.1021/jo0265939
(2003)Doi:10.1016/j.tet.2007.10.101
(2008)Doi:10.1016/j.jics.2021.100099
(2021)Doi:10.1039/b301824p
(2003)
