Enantioface-differentiating Addition of Butyllithium to Acetophenone by the Use of ((1S,2S,5S)-3--2-pinanols as Chiral Ligands

DOI: 10.1246/bcsj.58.1329

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1329 - 1330 (1985)

Update date:2022-08-15

Topics:

Authors:

Kawakami, Yuhsuke

Aoki, Toshiki

Yamashita, Yuya

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Article abstract of DOI:10.1246/bcsj.58.1329

Butyllithium and acetophenone gave optically active 2-phenyl-2-hexanol (33percent e.e.) in good yield in the presence of (1S,2S,5S)-3<(S)-2-methoxy-1-alkylethylimino>-2-pinanol (1).

Full text of DOI:10.1246/bcsj.58.1329

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Product name:Benzenemethanol, a-butyl-a-methyl-, (S)-

Cas No:19641-54-4

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