Synthesis of chiral Rh-bichep complexes, highly efficient catalysts for asymmetric hydrogenations

DOI: 10.1016/S0040-4039(00)92297-4

Source and publish data:

Tetrahedron Letters p. 4745 - 4748 (1991)

Update date:2022-08-16

Topics:

Authors:

Chiba, Takeshi

Miyashita, Akira

Nohira, Hiroyuki

Takaya, Hidemasa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92297-4

Chiral cationic and neutral Rh complexes RhX(bichep)(nbd) (X=Cl,ClO₄; NBD=norbornadiene;bichep=2,2′-bis(dicyclohexylphosphino)-6,6'-dimethyl-l, r-biphenyl) are highly active and excellent catalysts for enantioselective hydrogenation of prochiral olefms and ketones under mild reaction conditions.

Full text of DOI:10.1016/S0040-4039(00)92297-4

Products guided by the article

Product name:Alanine, N-benzoyl-3-phenyl-, ethyl ester, DL-

Cas No:19817-70-0

R&D Labs maybe for 19817-70-0

SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Beijing Huikang Boyuan Chemical Tech Co.,LTD

Contact:+86-10-68862197

Address:No.7 Haiying Road,Science City,Fengtai District,Beijing,China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Shanghai Biobond Pharmaceutical Co.,Ltd

website:http://www.sh-biobond.com/EnglishIndex.aspx

Contact:021-68719686 /18939786273/ 18917373795

Address:Shanghai Zhangjiang

Relevant to this article

Concise asymmetric syntheses of the (+)-2-C-methyltetritol isomers

Doi:10.1016/j.tetasy.2008.09.002
(2008)
Hierarchically nanostructured porous TiO₂(B) with superior photocatalytic CO₂ reduction activity

Doi:10.1007/s11426-017-9174-9
(2018)
σ- versus π-activation of alkynyl benzoates using B(C₆F₅)₃

Doi:10.3390/molecules20034530
(2015)
Support effect in the gas phase oxidation of ethanol over nanoparticulate gold catalysts

Doi:10.1039/c1nj20297a
(2011)
The nickel-substituted quasi-Wells-Dawson-type polyfluoroxometalate, [Ni^II(H₂O)H₂F₆NaW₁₇O ₅₅]^9-, as a uniquely active nickel-based catalyst for the activation of hydrogen peroxide and the epoxidation of alkenes and alkenols

Doi:10.1002/1521-3765(20001016)6:20<3722::AID-CHEM3722>3.0.CO;2-8
(2000)
Pyrrolidine-containing polypyridines: New ligands for improved visible light absorption by ruthenium complexes

Doi:10.1021/jo051994k
(2006)

Article Doi