Mechanistic studies on the photochemical deprotection of 3′,5′-dimethoxybenzoin esters

DOI: 10.1562/2006-02-07-RA-798

Source and publish data:

Photochemistry and Photobiology p. 1258 - 1264 (2006)

Update date:2022-08-29

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Authors:

Pirrung, Michael C.

Ye, Tong

Zhou, Zheng

Simon, John D.

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Article abstract of DOI:10.1562/2006-02-07-RA-798

Several mechanistic alternatives proposed for the photochemical deprotection of dimethoxybenzoin esters are presented. Both experimental and theoretical evidence suggest the mechanism is heterolysis of the singlet excited state to form a carboxylate and t

Full text of DOI:10.1562/2006-02-07-RA-798

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