Easy preparation of enoxysilanes from aldehydes and ketones catalyzed by samarium diiodide

DOI: 10.1055/s-1997-1514

Source and publish data:

Synthesis p. 68 - 72 (1997)

Update date:2022-08-11

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Authors:

Hydrio, Jerome

Van De Weghe, Pierre

Collin, Jacqueline

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Article abstract of DOI:10.1055/s-1997-1514

Ketones and α-substituted aldehydes are converted to trimethylsilyl enol ethers by reaction with the trimethylsilyl ketene acetal of methyl isobutyrate in dichloromethane in presence of a catalytic amount of samarium diiodide.

Full text of DOI:10.1055/s-1997-1514

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