Easy preparation of enoxysilanes from aldehydes and ketones catalyzed by samarium diiodide

DOI: 10.1055/s-1997-1514

Source and publish data:

Synthesis p. 68 - 72 (1997)

Update date:2022-08-11

Topics:

Authors:

Hydrio, Jerome

Van De Weghe, Pierre

Collin, Jacqueline

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-1514

Ketones and α-substituted aldehydes are converted to trimethylsilyl enol ethers by reaction with the trimethylsilyl ketene acetal of methyl isobutyrate in dichloromethane in presence of a catalytic amount of samarium diiodide.

Full text of DOI:10.1055/s-1997-1514

Products guided by the article

Product name:Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]trimethyl-

Cas No:19980-19-9

R&D Labs maybe for 19980-19-9

Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China

Relevant to this article

MOF-Templated Assembly Approach for Fe₃C Nanoparticles Encapsulated in Bamboo-Like N-Doped CNTs: Highly Efficient Oxygen Reduction under Acidic and Basic Conditions

Doi:10.1002/chem.201701389
(2017)
Catalytic behavior of copper(II) chelate complexes sterically held in zeolite large cavities and fixed on its outer surface by a topological anchor

Doi:10.1134/S1070363209120019
(2009)
Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives

Doi:10.1016/j.jfluchem.2015.07.020
(2015)
Regioselective reductive demethoxylation of 3,4,5-trimethoxystilbenes

Doi:10.1016/j.tet.2003.08.009
(2003)
Synthesis of alkyl sulfones from alkenes and tosylmethylphosphonium iodide through photo-promoted cc bond formation

Doi:10.1246/CL.200530
(2020)
Diffuse scattering of neutrons in thermally oxidized silicon

Doi:10.1016/S0921-4526(96)00515-7
(1997)

Article Doi