Journal of Physical Chemistry p. 409 - 414 (1990)
Update date:2022-08-11
Topics:
Sayyed, Basseera A.
Stair, Peter C.
C-H bond activation was studied via pulsed laser irradiation of oxides in a methane atmosphere.Carbon monoxide was the major product observed at low power densities and room temperature.Significant amounts of C2 products, ethane, ethylene, and acetylene were formed.CO, C2H6, C2H4, and C2H2 are assigned as primary products of the reaction.Laser-induced methane activation produces *CH3 and :CH2 radical species in the gas phase via a plasma mechanism and is utilized as a tool to study radical-oxide surface interactions.These reactions are surface sensitive as evidenced by the changes in conversion and product selectivity as a function of oxide pretreatment and oxides used.
View MoreContact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Jinan Hongfangde Pharmatech Co.LTD
Contact:0531-88870908
Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
Changzhou Medi-tech Bioscientific Co., Ltd.
Contact:86-519-83246372
Address:Number 115 Menghedadao Road, Changzhou, Jiangsu, China
website:http://www.debyesci.com
Contact:+85221376140
Address:Rm. 19C, Lockhart Ctr., 301-307 Lockhart Rd., Wan Chai
Doi:10.1021/j100085a042
(1994)Doi:10.1021/ja00461a024
(1977)Doi:10.1016/j.tetlet.2009.08.029
(2009)Doi:10.1016/0021-9614(80)90115-9
(1980)Doi:10.1021/ja00720a061
(1970)Doi:10.1021/jo0607663
(2006)