THE UV PHOTOLYSIS OF AZIDOMETHANE AND 3-AZIDOPROPYNE IN NITROGEN MATRICES

DOI: 10.1016/0022-2860(84)80048-4

Source and publish data:

Journal of Molecular Structure p. 197 - 200 (1984)

Update date:2022-08-11

Topics:

Authors:

Braathen, G. O.

Klaboe, P.

Nielsen, C. J.

Priebe, H.

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Article abstract of DOI:10.1016/0022-2860(84)80048-4

IR spectra of azidomethane, 3-azidopropyne and 3-azido-1-d-propyne in nitrogen matrices have been recorded during UV photolysis.In contrast to the simple photolytic reaction of matrix isolated azidomethane (azidomethane -> methyleneimine -> HCN + HNC), 3-azidopropyne apparently displays more complex reaction paths.

Full text of DOI:10.1016/0022-2860(84)80048-4

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