Homogeneous Catalytic Activation of C-N Bonds. Alkyl Exchange between Tertiary amines.

DOI: 10.1039/c39800000753

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 753 - 754 (1980)

Update date:2022-08-29

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Authors:

Shvo, Youval

Laine, Richard M.

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Article abstract of DOI:10.1039/c39800000753

We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of Et3N and Pr3N with either Ru3(CO)12, Os3(CO)12, or Ir4(CO)12 and water leads to very efficient alkyl exchange.

Full text of DOI:10.1039/c39800000753

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