Journal of the American Chemical Society p. 7034 - 7041 (1992)
Update date:2022-08-12
Topics:
Modarelli, David A.
Morgan, Scott
Platz, Matthew S.
Photolysis of 3,3-dimethyldiazirine produces an electronically excited singlet state which decays by at least three competitive pathways: (1) fluorescence, (2) nitrogen extrusion and carbene formation, and (3) α-hydrogen migration and propylene formation concurrent with nitrogen extrusion. The temperature dependence of the fluorescence intensity was determined.
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