Carbene formation, hydrogen migration, and fluorescence in the excited states of dialkyldiazirines

DOI: 10.1021/ja00044a013

Source and publish data:

Journal of the American Chemical Society p. 7034 - 7041 (1992)

Update date:2022-08-12

Topics:

Authors:

Modarelli, David A.

Morgan, Scott

Platz, Matthew S.

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Article abstract of DOI:10.1021/ja00044a013

Photolysis of 3,3-dimethyldiazirine produces an electronically excited singlet state which decays by at least three competitive pathways: (1) fluorescence, (2) nitrogen extrusion and carbene formation, and (3) α-hydrogen migration and propylene formation concurrent with nitrogen extrusion. The temperature dependence of the fluorescence intensity was determined.

Full text of DOI:10.1021/ja00044a013

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