Highly enantioselective reduction with novel, bridged NADH models

DOI: 10.1002/anie.199712071

Source and publish data:

Angewandte Chemie - International Edition in English p. 1207 - 1211 (1997)

Update date:2022-08-10

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Authors:

Kanomata

Nakata Nakata

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Article abstract of DOI:10.1002/anie.199712071

Biomimetic reduction of benzoylformate to mandelate with 97-99% ee was achieved with the diastereomeric, bridged NADH models (S.S)-1 and (R.S)-1. The oligomethylene bridge acts as an 'enzyme wall' and hinders the approach of the substrate from one side of

Full text of DOI:10.1002/anie.199712071

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