
Angewandte Chemie - International Edition in English p. 1207 - 1211 (1997)
Update date:2022-08-10
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Kanomata
Nakata
Biomimetic reduction of benzoylformate to mandelate with 97-99% ee was achieved with the diastereomeric, bridged NADH models (S.S)-1 and (R.S)-1. The oligomethylene bridge acts as an 'enzyme wall' and hinders the approach of the substrate from one side of
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