Chemistry of Heterocyclic Compounds p. 193 - 200 (1983)
Update date:2022-08-17
Topics:
Benders, Yu. A.
Stradyn', Ya. P.
Baider, L. M.
Baumane, L. Kh.
Gavar, R. A.
The character of the products of one-electron reduction of 2-pyridinia-1,3-indandiones (of the phthalone and ylid types) in aprotic media was studied by means of EPR spectroscopy.Free radicals with semidione structures are formed; their hfs constants are presented.Radicals with pyridinium structures are formed only under the condition of the presence of a strong electron acceptor (a cyano group) in the pyridinium ring of the molecule.The formation of unstable intermediates with dimeric structures is postulated as a result of studies by means of cyclical voltammetry.
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