Journal of the Chemical Society - Faraday Transactions p. 3045 - 3054 (1995)
Update date:2022-08-11
Topics:
Biggs, Peter
Canosa-Mas, Carlos E.
Fracheboud, Jean-Marc
Marston, George
Shallcross, Dudley E.
Wayne, Richard P.
A discharge-flow system equipped with a laser-induced fluorescence cell to detect the methoxyl radical and a quadrupole mass spectrometer to detect both the chlorine monoxide and chlorine dioxide radicals has been used to measure the rate constants for the reactions CH3 + ClO -> products (1) CH3O + ClO -> products (2) CH3 + OClO -> products (3) CH3O + OClO -> products (4) at T 298 K and P = 1-3 Torr.The observed products of these reactions are CH3O for reaction (1), HOCl for reaction (2), and CH3O and ClO for reaction (3).For reaction (4), CH3OCl is a possible product.The rate constants derived for reactions (1)-(4) are: k1 = (1.3 +/- 0.4)E-10 cm3 molecule -1 s-1; k2 = (1.3 +/- 0.3)E-11 cm3 molecule-1 s-1; k3 = (1.6 +/- 0.3)E-11 cm3 molecule-1 s-1; k4 = (1.5 +/- 0.5)E-12 cm3 molecule-1 s-1.The likely mechanism for (1)-(4) are briefly discussed.
View Moreshandong lukang animal & plant drug trading co.,ltd.
Contact:15853765968
Address:floor 9, lukang ,jingying building,#173,taibai building west road,jining city,shandong,china
Suzhou Kangrun Pharmaceutical, Inc
Contact:86-512-63912376，63913329
Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd
Contact:+86-0517-87036900
Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Doi:10.1021/jo970011j
(1997)Doi:10.14233/ajchem.2019.21901
(2019)Doi:10.1021/ic50050a041
(1967)Doi:10.1021/ac060509y
(2006)Doi:10.1021/j150613a028
(1981)Doi:10.1016/j.bmc.2005.06.046
(2005)
