Chemistry Letters p. 625 - 628 (1988)
Update date:2022-08-16
Topics:
Matsuda, Yoshihisa
Koshima, Hiroaki
Nakamura, Koichiro
Murakami, Yukito
Photochemical epoxidation of olefins was catalyzed by a molybdenum porphyrin in benzene under aerobic conditions.The catalytic reaction rate was somewhat lower than that observed for the similar reactions catalyzed by the corresponding niobium complex.A reaction mechanism, involving cooperative interaction of an olefin and dioxygen with the molybdenum(V) species, was postulated.
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