Chemistry Letters p. 565 - 566 (1992)
Update date:2022-08-11
Topics:
Kato, Teiji
Akiyama, Hideyuki
Yoshida, Masaaki
A-T-isobars of octadecylurea monolayers were measured.This is the first direct observation that the monolayers exhibited a first-order phase transition accompanying discontinuous molecular area contraction with increasing temperature.This may be due to the "fusion" of a hydrogen bonded bulky structure of urea head groups in the monolayers at the water surface.
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