Enantioselective hydrosilylation of ketones with a chiral titanocene catalyst

DOI: 10.1021/ja00105a006

Source and publish data:

Journal of the American Chemical Society p. 11667 - 11670 (1994)

Update date:2022-08-04

Topics:

Authors:

Carter, Mary Beth

Schi?tt, Birgit

Gutiérrez, Alberto

Buchwald, Stephen L.

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Article abstract of DOI:10.1021/ja00105a006

The first efficient asymmetric hydrosilylation of aromatic ketones with an early transition metal chiral catalyst affords alcohols with excellent enantioselectivity. The reaction is general for aromatic ketones and exhibits a moderate degree of functional group compatibility.

Full text of DOI:10.1021/ja00105a006

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