Tetrafluorosilane is a mild and very selective reagent for the cleavage of silyl-protected alcohols

DOI: 10.1016/S0040-4039(00)74192-X

Source and publish data:

Tetrahedron Letters p. 2289 - 2290 (1992)

Update date:2022-08-16

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Authors:

Corey Corey

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Article abstract of DOI:10.1016/S0040-4039(00)74192-X

Silyl ethers are cleaved by SiF₄ in CH₂Cl₂ or CH₃CN at a rate which depends strongly on the steric screening of the ether oxygen, providing a promising method for selective desilylation under mild conditions.

Full text of DOI:10.1016/S0040-4039(00)74192-X

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