Detection of a Metallo-intermediate and Geometrical Isomerizations in an Oxidative Cyclisation of a Heterocyclic Hydrazone with Mercury(II) Acetate

DOI: 10.1039/c39810000376

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 376 - 377 (1981)

Update date:2022-08-16

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Authors:

Butler, Richard N.

Johnston, Sean M.

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Article abstract of DOI:10.1039/c39810000376

Oxidative cyclisation of the E-isomer of 2-pyridylcarbaldehyde 2-pyridylhydrazone with mercury(II) acetate involved an amino-N-mercurio intermediate with a Z-structure and an E -> Z -> E series of isomerizations.

Full text of DOI:10.1039/c39810000376

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