Detection of a Metallo-intermediate and Geometrical Isomerizations in an Oxidative Cyclisation of a Heterocyclic Hydrazone with Mercury(II) Acetate

DOI: 10.1039/c39810000376

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 376 - 377 (1981)

Update date:2022-08-16

Topics:

Authors:

Butler, Richard N.

Johnston, Sean M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39810000376

Oxidative cyclisation of the E-isomer of 2-pyridylcarbaldehyde 2-pyridylhydrazone with mercury(II) acetate involved an amino-N-mercurio intermediate with a Z-structure and an E -> Z -> E series of isomerizations.

Full text of DOI:10.1039/c39810000376

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-Pyridinecarboxaldehyde, 2-pyridinylhydrazone, (Z)-

Cas No:21945-38-0

R&D Labs maybe for 21945-38-0

Borun Chemical Co.,Ltd.

Contact:+86-574- 87178138; 87297407

Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong
Hangzhou Deli Chemical Co.,Ltd.

website:http://www.dlchemical.com

Contact:86 571 28006267

Address:Tangxi Industrial Area, Yuhang District, Hangzhou
Xiamen Huasing Chemicals Co.Ltd.

Contact:0086-592-6228397

Address:NO.24, Xinglin North 2nd Road,Jimei district

Relevant to this article

Macrocyclic Tetraimines: Synthesis and Reversible Uptake of Diethyl Phthalate by a Porous Macrocycle

Doi:10.1021/acs.joc.6b00768
(2016)
Generation, Trapping, and Adduct Rearrangement of 3-Phenylselenoalk-1-enylidene Carbenes: a Novel Direct Route to 1-Hetero-substituted 1-Vinylcyclopropanes

Doi:10.1039/c39880000751
(1988)
Elemental fluorine. Part 21. (1) direct fluorination of benzaldehyde derivatives

Doi:10.1021/op700194r
(2008)
Doi:10.1021/j100865a600
(1967)
Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe₃O₄ catalyst

Doi:10.1039/c2cc16620h
(2012)
Synthesis of Para (-)-Δ⁸-THC Triflate as a Building Block for the Preparation of THC Derivatives Bearing Different Side Chains

Doi:10.1021/acs.orglett.8b03907
(2019)

Article Doi