Journal of Organometallic Chemistry p. 319 - 322 (1984)
Update date:2022-08-11
Topics:
Seetz, Johannes W. F. L.
Heisteeg, Bartholomeus J.J. van de
Schat, Gerrit
Akkerman, Otto D.
Bickelhaupt, Friedrich
The reaction of the di-Grignard reagents BrMgCH2CR2CH2MgBr (2a: R = H; 2b: R = Me) with dichlorodimethylgermane gave 1,1-dimethylgermacyclobutane (1a) and its 3,3-dimethyl derivative 1b, respectively, in more than 95percent yield.
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