Journal of the Chemical Society. Chemical communications p. 806 - 807 (1982)
Update date:2022-08-11
Topics:
Davidson, Iain M. T.
Fenton, Andrew M.
Jackson, Peter
Lawrence, F. Timothy
Pyrolysis of the title compound to give ethene and a silabutadiene has the same Arrhenius parameters as pyrolysis of 1,1-dimethyl-1-silacyclobutane, whence the allylic stabilisation in a vinyl silyl radical is estimated to be = 29 kJ mol-1; some comments are also made on the stability of silabutadienes.
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