Journal of the Chemical Society. Chemical communications p. 1651 - 1653 (1986)
Update date:2022-08-25
Topics:
Cole, Philip A.
Robinson, Cecil H.
A methoxyhydroperoxide analogue (12) to a proposed aromatase intermediate has been synthesized by ozonolysis of metoxyvinyl compound (7) in the presence of methanol; it has been shown not to produce estrone with or without acetylation, but the free hydroperoxide apparently undergoes a facile, stereospecific intramolecular epoxidation.
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