Journal of the Chemical Society. Chemical communications p. 745 - 746 (1986)
Update date:2022-08-31
Topics:
Jiang, Xi-Kui
Li, Xing-Ya
Wang, Ke-Yang
The relative rates of formation of CH3(.) and CF3(.) from β-scission reactions of trifluoro-t-butoxy radical (1) have been measured to be about 10:1 by thermolysing both trifluoro-t-butyl hypochlorite (4) and bis(trifluoro-t-butyl) peroxydicarbonate (14) in CCl4 at 160 and 140 deg C.
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