Tetrahedron p. 3277 - 3290 (1986)
Update date:2022-08-30
Topics:
Snowden, Roger L.
The intramolecular Diels-Alder reactions of (E)- and (Z)-trimethylsilyl cyclopentadienyl ethers, (E)-6a and (Z)-6a, proceed with excellent stereo- and regioselectivity.Starting from the tricyclic keto ester 8, available from the former reaction, a stereoselective synthesis of (+/-)-sativene (26) is described.
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Doi:10.1002/ejoc.201700682
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