Formation of both primary and secondary N-alkylhemins during hemin-catalyzed epoxidation of terminal alkenes

DOI: 10.1021/ja00106a003

Source and publish data:

Journal of the American Chemical Society p. 21 - 29 (1995)

Update date:2022-08-11

Topics:

Authors:

Tian, Zong-Qiang

Richards, Joseph L.

Traylor, Teddy G.

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Article abstract of DOI:10.1021/ja00106a003

The N-alkylhemin formation during iron(III) porphyrin-catalyzed epoxidation of alkenes is studied in a homogeneous system using pentafluoroiodosobenzene (PFIB) as the oxidant. The system is a model for the enzyme cytochrome P-450. A second N-alkyl species

Full text of DOI:10.1021/ja00106a003

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