
Journal of the American Chemical Society p. 21 - 29 (1995)
Update date:2022-08-11
Topics:
Tian, Zong-Qiang
Richards, Joseph L.
Traylor, Teddy G.
The N-alkylhemin formation during iron(III) porphyrin-catalyzed epoxidation of alkenes is studied in a homogeneous system using pentafluoroiodosobenzene (PFIB) as the oxidant. The system is a model for the enzyme cytochrome P-450. A second N-alkyl species
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