Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 496 - 502 (1980)
Update date:2022-08-11
Topics:
Stock, Colin J.
Whittle, Eric
The photolysis of the vapour of perfluoro-n-butyric anhydride was studied at 20 and 227 deg C.The effective primary process is (n-C3F7CO)2O+hυ -> 2 n-C3F7+CO+CO2 and the overall decomposition is quantitatively described by the equation (n-C3F7CO)2O+hυ -> n-C6F14+CO+CO2.The quantum yields of products increase with temperature but are independent of pressure. (n-C3F7CO)2O was photolysed in the presence of cyclohexane vapour.For the reactions n-C3F7+c-C6H12 -> n-C3F7H+c-C6H11 kH 2n-C3F7 -> C6F14 kc we obtain, log kH/k1/2c = (4.99+/-0.12)-(23910+/-750)/Θ where Θ = 2.303RTJmol-1 and kH/k1/2c is in cm1/2mol-1/2s-1/2.
View MoreWeihao Chemtech (ChangZhou) Co., Ltd.(expird)
Contact:051989185693
Address:NO 217 huangshan Rd ,Changzhou
Contact:+44 7958 511245
Address:PO Box 469, Manchester, UK
Zouping Fuhai Technology Development Co., Ltd.
Contact:+0532-86934525 18660293207
Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Henan zhongda Biological Engineering Co., Ltd
Contact:86-28-18109029985
Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd
Contact:0086-10-64430626
Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Doi:10.1007/BF02547131
(1995)Doi:10.1039/ft9918703473
(1991)Doi:10.1021/ja0271678
(2002)Doi:10.1134/S0965544116090152
(2016)Doi:10.1039/b202352k
(2002)Doi:10.1021/jo00101a001
(1994)
