Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2017 - 2025 (1980)
Update date:2022-08-30
Topics:
Varadarajan, R.
Wells, Cecil F.
The rate of oxidation of formic acid by Co(III)aq has been measured in aqueous perchlorate media over a wide range of conditions using conventional and stopped-flow spectrophotometry.The order in a complex manner.The mechanism is resolved into two rate determining processes, each involving an intermediate Co(III)-HCOOH complex.These two complexes have an acid-base relationship involving two protons.Values for ΔH* and ΔS* together with the ratio of rates of oxidation of HCOOH and DCOOH are compared for a range of oxidizing ions.
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