
Tetrahedron Letters p. 3747 - 3750 (1997)
Update date:2022-08-30
Topics:
Lin, Yong-Shou
Yamamoto, Akio
Carbonylation of benzyl alcohol catalyzed by a palladium(0) complex and promoted by hydrogen iodide gives phenylacetic acid in excellent yields in aqueous systems. The catalysis is proposed to proceed through a benzylpalladium species formed by the oxidative addition of benzyl iodide, produced in situ by the interaction of benzyl alcohol with HI, to a Pd(0) species. Application of the carbonylation process to other arylmethanol analogs provided convenient means to prepare 3-isochromanone, 1,4-benzenediacetic acid, 2-hydroxybenzeneacetic acid and 2-naphthaleneacetic acid.
View More
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Shanghai doly chemical Co.,Ltd
Contact:+86-21-34716221
Address:No.328,WuHe Roard,MinHang,ShangHai China
Changzhou naidechemical Co.Ltd
Contact:+86-519-82589807
Address:NO.25,Houyang street,Jintan,Changzhou City
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd
Contact:86-0312-6615158
Address:No 42 fazhan street qingyuan county
Weifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Doi:10.1016/j.tetlet.2010.08.078
(2010)Doi:10.1039/c3nj01436c
(2014)Doi:10.1002/open.201500158
(2015)Doi:10.1063/1.3103277
(2009)Doi:10.1002/cphc.201701219
(2018)Doi:10.1039/c3ra40205c
(2013)