Chemistry Letters p. 589 - 592 (1986)
Update date:2022-08-04
Topics:
Kaise, Masahiro
Nishihara, Chizuko
Nozoye, Hisakazu
Someno, Kazuo
In the photochemical electron transfer reactions of t-alkylamine and p-benzoquinone in liquid, emissively spin-polarized transient anion radicals from p-benzoquinone (PBQ) and 2,5- or 2,6-di-t-butyl-p-quinone (25Q or 26Q) are exclusively produced by photo-excitation of benzophenone (BP) in a magnetic field.Transient radicals of quinones with different unpaired spin distribution are obtained at the onset of photolysis.
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