
Journal of Fluorine Chemistry p. 337 - 346 (1987)
Update date:2022-08-17
Topics:
Maeda, Minoru
Abe, Masayuki
Kojima, Masaharu
Bromofluorination of 4-tert-butyl-1-methylcyclohexene (I) using a combination of N-bromosuccinimide and tetra-n-butylammonium fluoride as a source of fluoride gave the vicinal bromofluorides in acceptable yield.Similar treatment of methyl 3α,7α-diacetoxy-5β-chol-11-ene-24-carboxylate (IV) afforded the 12α-bromo-11β-fluoro steroid (V) in good yield.
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