Photolysis of Alkynyl(phenyl)iodonium Salts. Remarkable Solvent Effect and Generation of Acids

DOI: 10.1246/cl.1992.2245

Source and publish data:

Chemistry Letters p. 2245 - 2248 (1992)

Update date:2022-08-31

Topics:

Authors:

Kitamura, Tsugio

Tanaka, Toshimasa

Taniguchi, Hiroshi

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Article abstract of DOI:10.1246/cl.1992.2245

Photolysis of alkynyl(phenyl)iodonium salts in CH2Cl2 resulted in major formation of iodobenzene, while the photolysis in EtOH, Et2O, or THF gave iodoalkynes as the main product.In addition to the organic products, acids were generated almost quantitatively by the photolysis and initiated polymerization of styrene.

Full text of DOI:10.1246/cl.1992.2245

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