The Bovine Serum Albumin-2-Phenylpropane-1,2-diolatodioxo-osmium(VI) Complex as an Enantioselective Catalyst for cis-Hydroxylation of Alkenes

DOI: 10.1039/c39830000769

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 769 - 770 (1983)

Update date:2022-08-10

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Authors:

Kokubo, Toshio

Sugimoto, Toyonari

Uchida, Toshio

Tanimoto, Shigeo

Okano, Masaya

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Article abstract of DOI:10.1039/c39830000769

The 1:1 complex between an osmate ester and bovine serum albumin was found to be effective as an enantioselective catalyst in the cis-hydroxylation of alkenes, affording diols in up to 68percent e.e. and turnover of the catalyst with tert-butyl hydroperoxide.

Full text of DOI:10.1039/c39830000769

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